- Discovered by a casting director in her New York City school cafeteria.
- Enjoys painting, ceramics, poetry, martial arts and horseback riding.
- Her father is Jean Sobieski, a New York City painter, and her mother, Elizabeth, is a writer.
- Has a younger brother, Robert Sobieski (b. 1989).
- Collects locks of hair from major stars appearing with her in films. Tom Cruise refused to participate when filming Eyes Wide Shut (1999).
- Her father is a descendant of Jan III Sobieski, king of Poland between 1674 and 1696. He has a title that he does not use.
- Bears an uncanny resemblance to Helen Hunt.
- Is fluent in French.
- Australian band Primitive Whore perform a song entitled 'Why Leelee Won't Love Me'.
- Is of Polish, Swiss, and Dutch heritage.
- Has size 10 feet.
- Born on the same day as figure skater Tara Lipinski and Prinsessan Madeleine, the Swedish Princess.
- In 2001, she matriculated with the class of 2005 at Brown University, but she has since taken time off to advance her career. She remains a popular topic of conversation of Brown students.
- Has an older sister.
- Youngest actress ever to portray Joan of Arc in a movie (Joan of Arc (1999) (TV)) and, by that, the one who is the most closest to the real age of the historical figure.
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